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543.422 Ѳ ̲ί ֲ̲ -ֲ в: ʲ ...

-- [ 11 ] --

. , [144-145], [146]. (.4.6) , , . . [127] , , . . ϳ (. 4.1), [140, 143, 147-148].

219 / (.4.3). 㳿 , , . 69 330 / , (.4.4).

, . , , . 108 -1, , . .

   

(1.20.4) 10-5 1873 817 22753 (2.01.0)10 (6.22.6)10

   

(1.40.2)10-5 2473 807 2116 (0.20.1)10 (1.61.0)10 , , , . ֳ , Ag , ( ). . . - , . ,

   

, [154]. [89]. - Ag (.4.7). . [89] . . [108]:

   

Tp(t) t;

Tend ;

Tbeg ;

p .

, [155]. ʳ , - end=2173 . (. 4.3). , , end. . 4.7, - . , ( ) .

糿 . ֳ , ( ) , ( ) , .

   

- [136-137, 156]. ֳ . (. 4.8). , , . , . 㳿 [156].

   

.4.8. ( 3.5 2.2 ) . [136] , , ..

, , . , - , :

[157], [158].

, . [38, 107] 㳿 , 326 / 272 /, . . , ZnO (0.3% 2000 ) [138, 159]. ֳ , .

㳿 185 / (. 4.5).

㳿 㳿 [160]. [22] , ZnO 428 /. , , 򳺿 , - G = H T S G 0. . 4.9 - .

   

ֳ , , . . 4.9. , 1200 . , 1170 ( - ) .

. 4.5 , 107 -1. . , . , , ZnO() + CO( ) Zn( ) + CO2 ( ).




140 .


C () + CO2 ( ) 2CO( ) , ( 2373 0.135 3/3 , 23 . % ) [68]. . , . , , .

CuO Cu2O [162].

糿 Zn . [127, 163] , 糿 糿 糿 ( 糿 , 糿 ). .

³, ( ) (. 4.1, 4.3, 4.5). , (, , ..). .

4.3.

.4.10 - , . ( ) - (. 4.10). (., , [88]). , (.

4.10), - . (. 4.10).



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